Catalysis And Its Industrial Applications

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, whilst purified hydrogen is injected into the catalyser. The hydrogen is usually under a pressure of a few atmospheres, but this is not indispensable. Indeed, it has been shown recently that reduction can take place even under reduced pressure (Zelinsky). For an account of the various kinds of apparatus employed, see Journ. Soc. Chem. Ind. , 1912, JJ, 1155- The two essentials of the process are concerned with the production of an active catalyst and with the problem of a cheap hydrogen supply....
With regard to the former, some form of nickel is generally employed, because of its low cost and high efficiency. But recently palladium has received some attention, on account of its extreme efficiency, though its initial cost is against it ; whilst other metals, e. G. , platinum, copper, iron, etc. , have been used to some extent.
The hydrogen necessary for the process is now available from several sources. By one method, suitable for large plants, steam is decomposed by heated iron sponge with the formation of hydrogen and ferric oxide, the iron of the latter being regenerated by reduction with water-gas.


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