Activity And Concentration Transport Numbers And Boundary Potential

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00910 0. 00943 0. 00901 0. 00933 n/I2O n/3O 0. 01130 0. 01147 0. 01187 0. 01133 0. 01173 n/i$o n/30 0. 01315 0. 01337 0. 01384 0. 01324 0. 01371 n/iSo w/3o 0. 01475 0. 01488 0. 01541 0. 01474 0. 01527 n/300 n/30 0. 01898 0. 01916 0. 01984 0. 01899 0. 01967 TABLE IV SUMMARY OF VALUES FOR E2 Calculated Cone. Diff.
Measured New formula Old formula N c = 832 N c = 826 N c = 832 N c = 826 n/30 - n/s 0. 07163 0. 07140 0. 07046 0. 07282 0. 07188 n/6o - n/so 0. 02773 0. 02789 0. 02776 0. 02833 0. 02820
... n/go - n/^o 0. 04446 0. 04463 0. 04431 0. 045 1 1 0. 04479 n/i2o n/3o 0. 05573 0. 05611 0. 05570 0. 05681 0. 05640 w/i5o n/3o 0. 06535 0. 06555 0. 06508 0. 06618 0. 06571 n/iSo w/3o 0. 07299 0. 07304 0. 07251 0. 07370 0. 07317 w/300 w/30 0. 09488 0. 09406 0. 09338 0. 09484 0. 09416 By substituting the measured values in the formula for the electromotive force of concentration cells without boundary potential, the activity ratios for the various concentration differences were calculated. These are presented in Table V, together with the concentration ratios for the same concen- tration differences calculated from conductivity measurements.

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