Ceramic Chemistry

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. 04-0 05 Phosphorus 0. 03-0. 09 1. 0- 1. 8 Silicon . 01 2. 0 0. 04-0. 06 0. 5-0. 7 Carbon . . 10 3. 5 But Griinwald gives the manganese for sheet metal as 0. 23-0. 35 per cent. The metal, before enamelling, must be pickled or sand- blasted. An enamel on metal must fuse between 850-1000 C. It must mature in a few minutes and be fluid enough to lie evenly. It must withstand sudden changes of tempera- tures, and fit the iron as nearly as possible. And according to its purpose, it must be more or ...less acid-proof. In order to lower its melting point, it is made very rich in fluxes, and the ingredients are previously fritted. The coefficient of expansion must be raised as much as possible. Iron has the coefficient of cubical expansion (3a) x 10" 7 of 4 . 2, and copper is greater still. Pottery and glazes, on the other hand, are 2. 0-3. 0; so that the constituents of an enamel require judicious selection to fit a metal. Winkel- mann and Schott's figures (1894), revised and extended by Mayer and Havas (1911), and confirmed practically by Wolf (1911), are as follows for the expansion of the various oxides in a glaze or enamel, as compared with the 4.

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