Chemical Combination Among Metals

Cover Chemical Combination Among Metals
Chemical Combination Among Metals
Michele Giua
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Ber. , 14, 1433 (1881), J. Prakf. Chem. , 17, 346 (1839). C. R. , 88, 180 (1870). Wied. Ann. , 43, 111 (1891). Jahresber. , 1850, p. 333 ; 1863, p. 280. Zeit. Anorg. Chem. , 75. 41 (1912). HOMOPOLAE INTERMETALLIC COMPOUNDS. 209 pounds, Al 2 Ce and Al 4 Ce, have melting points much above those of their components. The curve (Fig. 113) shows two maxima, one very pronounced at about 1460 and 33 per cent, of cerium due to the compound CeAl 2, and the other, not so pronounced, at about 614, correspo...nding to Ce 3 Al. The asymmetry of the latter maximum is due in all probability to the compound Ce 3 Al being strongly dissociated, while the FIG. 113. Compound Ce 2 Al is less dissociated. The latter compound, formed at 33 per cent, of aluminium, melts at 595 with decomposition into CeAl and a melt ; CeAl separates primarily in beautiful prisms which at 780 split up into CeAl 2 and a fused mixture. Above 700, between 35 and 50 per cent, of aluminium, weak thermal effects are noted which may be due to the occurrence of lanthanium and didymium in the cerium used for experiment.

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