Elements of Chemistry Theoretical And Practical

Cover Elements of Chemistry Theoretical And Practical
Elements of Chemistry Theoretical And Practical
Robert Kane
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The chloride of silicon is a colourless liquid, denser than water ; it boils at 124; in contact with water, it is resolved into silica and hy- drochloric acid, from whence its formula must be SiCl 2 .
Fluoride of Silicon. This is the most remarkable compound of sili- con, after silicic acid ; it is a gas colourless and transparent : to prepare it, fluor spar and sand, or glass in powder, are mixed together and heated in -contact with oil of vitriol, the mass swells up very much, so that a large
... vessel must be employed. In this reaction we may look upon water as being decomposed or not, as the results may be explained in either way. Thus, the oxygen of the silica may combine with the calcium, forming lime, and this with the sulphuric acid, whilst the silicon unites with the fluorine of the fluor spar. Or, water being de- composed, hydrofluoric acid and lime may be first produced, and the former reacting on the silica may reproduce water, and form fluoride of silicon. I prefer to omit here, as I did when describing the forma- tion of chlorine, all the unnecessary theoretic agency of the water, and to express the decomposition as 2(S0 3 .

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