Some Conditions Affecting the Usefulness of Iron Oxide for City Gas Purification

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Some Conditions Affecting the Usefulness of Iron Oxide for City Gas Purification
William Albert Dunkley
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\ \ ^ -2/5 \ \ \ V t \ \ \ L *v \ \ r< c? ^\ 's^ \ \ tv //} > S "^^fc^ k - ^^.^ s ^^^^ ^^ ^^^ ^ 1 , N> tQ iS to *".. 3-4 X % NSI """"""1 M ** M * ^"~K ^ -. < n """ i Foul Fou/ Fou/ Fou/ FIG. 6. ACTIVITIES AND CAPACITIES OF THREE TYPICAL OXIDES DURING FOUR SUCCESSIVE FOULINGS NOTE Curves marked "A" denote activity in percentages of hydrogen sulphide de- composed per minute per unit of ferric oxide; curves marked "C" denote capacity in per- centages of hydrogen sulphide decomposed per unit of ferric oxide during one complete fouling. 42 ILLINOIS ENGINEERING EXPERIMENT STATION to completely revivify might be due to two causes: (1) inability of the oxygen of the air to gain access to the iron sulphide on account of the free sulphur; and (2) the formation of sulphides which do not readily revivify. It is probable that both these conditions are re- sponsible for the deterioration of oxide in laboratory tests, whereas in plant operation the presence of tar vapors and cyanides in coal gas further tends to the coating of the active material and the forma- tion of inert compounds, thus hastening the deterioration of oxide.

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