Some Organic Compounds of Mercury
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1 An analogous reaction occurs and a similar product is obtained with the acetylated ortho diphenyl derivative. Both the complex organomercuric oxides were converted to the original chlorides by treatment with acetic acid and sodium chloride. The same conversion was brought about by treatment with ethyl acetate and then with sodium chloride solution. 2 All the organic mercury com- pounds studied reacted with ammonium sulfide only on standing. They reacted slowly with cold cone, hydrochloric aci...d, but rapidly with the hot acid to give inorganic mercury salts which formed an immediate pre- cipitate with hydrogen sulfide.
Experimental.
Preparation of the 0- and ^-Hydroxyphenylmercuric Chlorides. Twelve g. Of phenol (about 1. 5 molecules) was heated on the steam-bath and 25 g. Of mercuric acetate was added gradually while the mixture was stirred constantly. When all the acetate had dissolved, boiling water was added and the mixture was boiled for a few minutes. Then a hot solution of 5 g.
What to read after Some Organic Compounds of Mercury?
You can find similar books in the "Read Also" column, or choose other free books by Edmund Burrus Middleton to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
1 An analogous reaction occurs and a similar product is obtained with the acetylated ortho diphenyl derivative. Both the complex organomercuric oxides were converted to the original chlorides by treatment with acetic acid and sodium chloride. The same conversion was brought about by treatment with ethyl acetate and then with sodium chloride solution. 2 All the organic mercury com- pounds studied reacted with ammonium sulfide only on standing. They reacted slowly with cold cone, hydrochloric aci...d, but rapidly with the hot acid to give inorganic mercury salts which formed an immediate pre- cipitate with hydrogen sulfide.
Experimental.
Preparation of the 0- and ^-Hydroxyphenylmercuric Chlorides. Twelve g. Of phenol (about 1. 5 molecules) was heated on the steam-bath and 25 g. Of mercuric acetate was added gradually while the mixture was stirred constantly. When all the acetate had dissolved, boiling water was added and the mixture was boiled for a few minutes. Then a hot solution of 5 g.
What to read after Some Organic Compounds of Mercury?
You can find similar books in the "Read Also" column, or choose other free books by Edmund Burrus Middleton to read onlineMoreLess
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