The Passivification of Iron By Nitric Acid

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0347 0. 1668 0. 00220 10 0. 0452 0. 1584 0. 00197 o . 0340 0. 1651 0. 00218 0. 0454 o. 1601 0. 00197 12 0. 0413 0. 1618 0. 00222 12 0. 0544 0. 1544 . 00202 0. 0427 o. 1614 0. 00230 0. 0547 0. 1540 o . 00203 The Passivification of Iron by Nitric Acid 633 From these tables it is evident that there is a continuous rate of solution of iron even in passivifying acids. The results further show that while the absolute amounts of solution (values of x) is noticeably greater in the stronger than in the ...less strong acid, nevertheless, this increase is not sufficiently great to make up for the theoretical effect (as demanded by the mass action law) of the increased concentration of the acid used. This accounts for the fact that while in the stronger acid the values of x are larger, the values of K are smaller. This points, of course, to an increased inhibiting effect with increasing concentrations, even with these extremely strong acids.
The Time-Temperature-Concentration Function From the data given in Table 2, a number of cross com- pilations might be made.


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