The Phase Rule

Cover The Phase Rule
The Phase Rule
Wilder D Wilder Dwight Bancroft
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1 Reicher, Ibid, x, 221, (1887).
i8o The Phase Rule peratures below that of the quintuple point. The Theorem of Le Chatelier would tell us the direction of the change at the quintuple point if the heats of reaction were known. As this is generall) 7 not the case, we must content ourselves with an approximation. If we assume that no one of the compounds has a true melting point, the following rule holds good in all the instances yet studied. When one of the solid phases can split into the othe
...r two with addition or subtraction of water 1 the inversion point is a minimum temperature for that phase if the water be added to complete the reaction and a maximum temperature if the water be subtracted. 2 The following instances will illustrate this rule and at the same time furnish a list of the different systems in which quintuple points have been determined. At 3 one of the double sulfates of mag- nesium and potassium changes into the single sulfates with addition of water. 3 This is a minimum temperature for K 2 Mg(SO 4 ) 2 6H 2 O.

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