The Rise And Development of Organic Chemistry
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In the same way he distinguished monatomic, diatomic, and triatomic elements. To Gerhardt's types Kekule added the marsh-gas type, which is derived from tetratomic carbon. It must be distinctly pointed out that by the use of typical formulae, it was not intended to express the position or the arrangement of the atoms in a molecule ; they did not represent constitutional formulae, but were only formula of decomposition, used by common con- sent to express a certain number of reactions. One and t...he same compound could, therefore, be repre- sented by various types. Thus, for instance, methyl ether, which, according to Williamson, belonged to the water type, might also be referred to the double marsh- gas type, by assuming that it consisted of two residues of marsh gas kept together by one atom of oxygen H \0 H/ U CH ; a m HI CH 3 / HU H H C By replacing one atom of hydrogen in ammonia by methyl, we obtain methylamine, belonging to the am- monia type ; but it may also be looked upon as marsh gas in which one atom of hydrogen is replaced by amide ; or we may refer it to the hydrogen type and regard it as a compound of methyl with amide MIXED TYPES 73 CH 3 H Olefiant gas combines with bromine to form ethylene dibromide ; in this the bromine can be replaced by hydroxyl when ethylene glycol is formed.
What to read after The Rise And Development of Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Carl Schorlemmer to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
In the same way he distinguished monatomic, diatomic, and triatomic elements. To Gerhardt's types Kekule added the marsh-gas type, which is derived from tetratomic carbon. It must be distinctly pointed out that by the use of typical formulae, it was not intended to express the position or the arrangement of the atoms in a molecule ; they did not represent constitutional formulae, but were only formula of decomposition, used by common con- sent to express a certain number of reactions. One and t...he same compound could, therefore, be repre- sented by various types. Thus, for instance, methyl ether, which, according to Williamson, belonged to the water type, might also be referred to the double marsh- gas type, by assuming that it consisted of two residues of marsh gas kept together by one atom of oxygen H \0 H/ U CH ; a m HI CH 3 / HU H H C By replacing one atom of hydrogen in ammonia by methyl, we obtain methylamine, belonging to the am- monia type ; but it may also be looked upon as marsh gas in which one atom of hydrogen is replaced by amide ; or we may refer it to the hydrogen type and regard it as a compound of methyl with amide MIXED TYPES 73 CH 3 H Olefiant gas combines with bromine to form ethylene dibromide ; in this the bromine can be replaced by hydroxyl when ethylene glycol is formed.
What to read after The Rise And Development of Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Carl Schorlemmer to read onlineMoreLess
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