Introduction to Metallography

Cover Introduction to Metallography
Introduction to Metallography
Paul Goerens
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49.
A L UMINIUM-SIL VER 97 it appears from the researches of Gautier. Fig. 83 shows the diagram constructed by Petrenko. In it the line AgDCFGAl marks the commencement of freezing. At the point D the alloy freezes exactly like a chemical compound AlAg 2 ; it possesses only one arrest-point, and the frozen mass consists of homogeneous 1000 9615 950 657 450 10 ZO 30 40 50 60 70 Atomic percentages of aluminum.
FIG. 83. Diagram of the aluminium-silver alloys (Petrenko).
crystals. The freezing of al
...loys between Ag and D proceeds in such a way that mixed crystals Agd eventually separate from the composition AgD ; dD does not correspond, however, as one would expect, to a eutectic, but to the freezing of the compound AlAg 3 . This is the second case where the separating mixed crystals gradually approximate to the composition of a com- pound (see aluminium-magnesium). As the latter undergoes an H 9 8 THE PHYSICAL MIXTURE allotropic change at a temperature lying somewhat higher than 600 C, a horizontal line d'D' occurs in the diagram corresponding to this transformation.

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