The Manufacture of Alum And the Sulphates And Other Salts of Alumina And Iron

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The Manufacture of Alum And the Sulphates And Other Salts of Alumina And Iron
Lucien Geschwind
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This reaction may be observed when a solution of aluminate is agitated out of contact with carbon dioxide ; and it must be borne in mind during the lixiviation of calcined bauxite with soda, since the residue may easily retain alumina precipitated in this manner. FIG. 97. Carbonating the aluminate solution. A, Pan ; B, agitator ; G, steam pipe ; C, feed pipe for aluminate solution ; E, blow-off; D, CO 2 pipe ; F, effluent ; H, reservoir. 144 MANUFACTURE OF ALUMINIUM SULPHATE The following are t...he result of sundry experiments made by the author : A clear solution containing 63-49 grms. Of alumina and 66-96 grms. Of soda (Na 2 O) per litre was treated with a little aluminium hydroxide and shaken up cold in a corked flask ; precipitation ensued, the liquid gradually becoming poorer in alumina in the following proportion : After 48 hours the solution contained 35-78 grms. Of A1 2 O 3 per litre, ,, 62 29-44, , no, ,, 2i'8o, , 134 15-50 but no decrease followed when the agitation was further pro- longed.

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