A Dictionary of Applied Chemistry volume 3

Cover A Dictionary of Applied Chemistry volume 3
A Dictionary of Applied Chemistry volume 3
Thomas Edward Thorpe
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The acid HA+HgO forms needles soluble in 4800 parts of water at 21 or in 238 parts of boiling water ; the 'potassium salt KA scales, soluble in 280 parts of water at 19, or in 67 parts at 100 ; the sodium salt NaA scales or tables, soluble in 885 parts of water at 24, or in 375 parts at 100 (Erdmann, Annalen, 1888, 247, 320). It is convertible into a-chloranaphthalene-8-sul'phonyl chloride, m. P. 101, and into 1 : 8-dichloronaphthalene (Armstrong and Wynne, Chem. Soc. Proc.
1895, 11, 84).
React
...ions. (1) From its sparingly soluble diazo- compound naphthasultone (the anhydride of o-naphthol-8-sulphonic acid) has been ob- tained (Erdmann, I. E. 344).
It couples with diazotised bases, and has been used as end component in disazo-dyes (Bayer, D. B. -P. 96083 of 1892; Eng. Pat. 1851 of 1893), or, like its phenvl derivative {ihid. D. B, . -P. 75571 of 1893), in the production of monazo dves (Leonhardt, D. R. -P. 108546; Eng. Pat. 24830 of 1898).
(2) When heated at 130 with phosphorus oxychloride it gives naphthasultam (Dannerth, J.


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