A Dictionary of Applied Chemistry volume 5

Cover A Dictionary of Applied Chemistry volume 5
A Dictionary of Applied Chemistry volume 5
Thomas Edward Thorpe
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Russ. Phys. Chem. Soc. 1910, 42, 40), titanium only forms solid solutions with nitrogen, but no definite compounds.
Titanium also forms a carbide (Shimer, Chem. News, 1887, 55, 156 ; Moissan, I. E. ; and Compt. Rend. 1897, 125, 839) ; a cyanonitride Ti(CN) 2 -3Ti 3 N 2 (Wohler, Annalen, 1850, 73 ; ibid. 34, 74, 212 ; Franck, Chem. Zeit. 1897, 21, 520 ; J. Soc. Chem. Ind. 1908, 809) ; and a silicide TiSi 2 (Honigsmid, Compt. Rend. 1906, 143, 224 ; J. Soc. Chem. Ind. 1909, 249).
Soluble double py
...rophosphates of titanium and alkali are prepared by mixing together alkali pyrophosphates and basic titanium sulphate (Barnes and Spence, Eng. Pat. 6329, 1906 ; J. Soc. Chem. Ind. 1907, 93).
Titanium phosphide TiP -forms a brittle mass with a metallic lustre. It bums when heated in air, is a conductor of electricity, is insoluble in dilute and in concentrated alkalis and acids (Gewecke, Annalen, 1908, 361, 79).
Titanic acid forms crystalline ihioeyanates of the type K 3 TiO(SCN) 4 H 2 O and double salts with pyridine (C 5 N 5 H) 2 H 2 TiO(SCN) 4, and quino- line (Rosenheim and Cohn, Zeitsch.


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