A Manual of Practical Physical Chemistry

Cover A Manual of Practical Physical Chemistry
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F. S. ) and the one liquid contact potential. In studying the connection between E. M. F. And the chemical changes which occur at the electrodes, what is measured is the E. M. F. Of the whole cell. Now, since this cell E. M. F. Includes the liquid contact potential, a quantity which has nothing to 166 ELECTROMOTIVE FORCE do with the electrode chemical changes but depends on differ- ences between ionic migration velocities, it is necessary that the liquid contact potential should either be evalu...ated by cal- culation or eliminated by modification of the experimental details. The elimination may be effected either by adding to the two electrode solutions an indifferent electrolyte, for example, potassium chloride, or by dipping the bent tube of each electrode vessel in a saturated solution of potassium chloride, or potassium nitrate, or ammonium nitrate, this intermediate solution there- fore serving to connect the two electrode solutions. When the liquid contact potential is thus eliminated, the cell E.

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