A Study of the Decomposition of Silicates By Barium Salts

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A Study of the Decomposition of Silicates By Barium Salts
Gilbert Hayes Whiteford
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0068 . 0111 . 0083 #4 . 0111 . 0203 . 0135 #5 . 0065 . 0243 . 0128 #6 . 0186 . 1603 . 01£3 #7 . 0023 . 0215 . 0185 Ko real advantage seems t4 be gained by the use of high temperatures in the decomposition other than to decrease this residue, except in the case of #6, - a garnet rock very rich in manganese. In the case of this specimen accurate checks of SiOg could not be obtained with so large a residue, while when decomposed at a high temperature it was quite easy to check the results within t...he limits of experimental error. With sodi\un carbonate this fusion strongly attached the crucible, forming a dark coating which only could be removed by long and repeated heatings with concentrated hydrochloric acid. The fusion with barium salts did not attack the crucible at all, not even dis- coloriTjg it. In all cases the mass decomposed at higher temper- atures formed a loosely sintered mass which was easily removed from the crucible, could easily be broken up with a stirring rod and readily went into solution, - in some case without any evolution of carbon dioxide -Ahen treated with hydrochloric acid.

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