A System of Inorganic Chemistry

Cover A System of Inorganic Chemistry
A System of Inorganic Chemistry
Sir William Ramsay
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6H 2 O = Ca(SH) 2 . 6H 2 O.
Hydrated polysulphides. Ca 2 S 2 . 3H 2 O ; SrS 4 . 6H 2 O, and others.
Preparation. Hydrated oxides, and hydroxides. 1. By direct addition. All of these oxides unite with water directly ; beryllium oxide shows least tendency ; calcium oxide unites with great evolution of heat ; the water is at first absorbed, and then the lumps of lime grow so hot as to evolve clouds of steam, and break up into a bulky white powder. This is the familiar opera- tion of "slaking lime.
... " The product is termed "slaked lime. " Barium oxide unites with water with so great an evolution of heat as to turn red hot when thrown into water. Calcium hydroxide is sparingly soluble in water, and the solubility diminishes with rise of temperature. At 15, 1 gram of calcium oxide dissolves in 779 grams of water ; at 20, in 791 grams ; and at 95, in 1650 grams. It would thus appear that calcium hydroxide loses water when heated even in contact with water, and hence shows no tendency towards further hydration.

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