A System of Volumetric Analysis

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This fact presents us with a method of separating mer- cury from the metals both of sub-groups 5 and 6.
The metals mentioned in the foregoing table may be separated into groups, in a solution containing them all, by the following process: Sulphuretted hydrogen is passed into the warm acidified solution, the precipitate is collected on a filter, and digested with potassium sulphide containing a little caustic potash, whereby the members of sub-group 6 are dissolved. The filtrate from the first p
...recipitate is neutralised by means of ammonia, and mixed with ammonium sulphide; the precipitate, con- taining the members of sub-groups 3 and 4, is digested with gentle heating with caustic potash, whereby the metals of sub-group 3 pass into solution. By boiling the filtrate from group II. With ammonium carbonate, the members of sub-group 2 are precipitated, while those of sub-group 1 remain in solution.
The following precautions must be attended to in carry- ing out this separation : In acidifying the original solution the addition of a large excess of acid must be avoided.


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