A Text book of Inorganic Chemistry

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Properties Argon, like all the other members of this group, is a colourless, odourless gas. Its density is 19. 94, and therefore its molecular weight is 39. 88. So far, all attempts to make argon enter into chemical combination have been fruitless, so that its atomic weight cannot be determined by the usual volumetric method (p. 1 15). It has, however, been determined by the following method that 'argon and the other gases of this group have only one atom in the molecule, so that the atomic and
... molecular weight are identical.
It can be shown 1 that the molecular heat 2 of a monatomic gas at 1 Physical Chemistry, p. 46.
2 The product of specific heat and molecular weight.
THE ELEMENTS OF THE HELIUM GROUP 209 constant volume, that is, the heat required to raise i mol of the gas i in temperature, is 3 calories, but more heat is required to raise a mol of a polyatomic gas i in temperature, as in this case heat is also absorbed in doing work within the molecules. Since it was found by experiment that the molecular heat of the inactive gases was 3 calories, it follows that they are monatomic.


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