A Text book of Medical Chemistry And Toxicology

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65 gm. ) largely diluted. The antidotes for it are the diluted acids, vinegar, lemon juice, and the oils with milk.
Sodium bicarbonate (NaHCO 3 ) (acid carbonate, monoso- dium carbonate) occurs in Vichy and many other alkaline mineral waters. It can be made by the Solvay ammonia process given above, or by the action of carbon dioxid on the normal carbonate. Its crystals are without water and are permanent in the air. It is soluble in water, imparting a saline taste and an alkaline reaction. As
...carbonic acid is a very weak acid and its salts are hydrolyzed in solution, all soluble carbonates dissociate enough hydroxyl to give an alkaline reaction, the carbonic acid remaining almost undissociated: Na 2 CO 3 + H 2 O Na', (HCO 3 )' + Na', (HO)'.
NaHCO 3 + H 2 O = Na-, (OH)' + H 2 CO 3 .
SODIUM 229 If the monosodium carbonate is put in water and boiled, it loses CO 2 and dissolves as the disodium carbonate. If this is evapo- rated rapidly a salt separates, called the sesquicarbonate, Na 4 H 2 (CO 3 ) 3, sometimes written Na 2 CO 3, NaHCO 3, 2H 2 O.


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