A Text book of Thermodynamics With Special Reference to Chemistry
A Text book of Thermodynamics With Special Reference to Chemistry
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(14) where 2?', = v . -. . . (15) is the increase of the number of rnols in the reaction.
144. Maximum Work of a Gas Reaction.
If a chemical reaction occurs spontaneously, the available energy of the system necessarily diminishes by an amount equal to the work which could be done by the system if the given change were executed reversibly. If the reaction occurs at con- stant temperature, this is equal to the diminution of free energy of the system, this being the energy available at constant te...mpera- ture. It is usual to refer to the work available at constant CHEMICAL EQUILIBRIUM IN GASEOUS SYSTEMS 331 temperature in a reversible change as the maximum ivork of the change, A T : A T = *! - * 2 = - A* . . . . (1) Its value depends only on the initial and final states and has a definite value for a given temperature at which a rever- sible isothermal process is executed, and given terminal states. Thus if 2 mols of hydrogen gas at a given volumetric molecular concentration HI, and 1 rnol of oxygen gas at a given concentra- tion H 2, are converted into 2 mols of steam at a given concen- tration Ha, all the gases having the same temperature, the maximum work has one definite value, no matter how the process FIG.
What to read after A Text book of Thermodynamics With Special Reference to Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by J R James Riddick Partington to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
(14) where 2?', = v . -. . . (15) is the increase of the number of rnols in the reaction.
144. Maximum Work of a Gas Reaction.
If a chemical reaction occurs spontaneously, the available energy of the system necessarily diminishes by an amount equal to the work which could be done by the system if the given change were executed reversibly. If the reaction occurs at con- stant temperature, this is equal to the diminution of free energy of the system, this being the energy available at constant te...mpera- ture. It is usual to refer to the work available at constant CHEMICAL EQUILIBRIUM IN GASEOUS SYSTEMS 331 temperature in a reversible change as the maximum ivork of the change, A T : A T = *! - * 2 = - A* . . . . (1) Its value depends only on the initial and final states and has a definite value for a given temperature at which a rever- sible isothermal process is executed, and given terminal states. Thus if 2 mols of hydrogen gas at a given volumetric molecular concentration HI, and 1 rnol of oxygen gas at a given concentra- tion H 2, are converted into 2 mols of steam at a given concen- tration Ha, all the gases having the same temperature, the maximum work has one definite value, no matter how the process FIG.
What to read after A Text book of Thermodynamics With Special Reference to Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by J R James Riddick Partington to read onlineMoreLess
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