A Textbook of Organic Chemistry

Cover A Textbook of Organic Chemistry
A Textbook of Organic Chemistry
A August Bernthsen
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Fu- marie Acid): H. C-C 6 H 4 -OH H-C-C 6 H 4 . : OH H-OOC-C-H H C-CO -O'lH o-Conmaric Coumarinic acid.
464 XXVI. AROMATIC ACIDS 3 : 4-Dihydroxy-cinnamic acid, Ca/eic add, (OH) 2 C 6 H 3 CH : CH C0 2 H, crystallizes in yellow prisms, and is obtained from caffetannic acid, whose mono-methyl ether is ferulic acid (from asafoetida); the isomeric umbellic acid or jp-hydroxy-o-coumaric acid readily changes into the anhydride corresponding to cou- marin, viz. Umbelliferone, C 9 H 6 C 3 ; this last-na
...med compound is present in varieties of Daphne.
Belated to the above is piperic acid: CH 2 C 6 H 3 . CH : CH CH : CH CO 2 H, a decomposition product of piperine (p. 540), which crystallizes in long needles.
B. Dibasic Acids The dibasic acids occupy exactly the same position in the aromatic series as the dibasic acids C n H 2n _ 2 4 do in the fatty. They contain two carboxyl groups; these may both be in the nucleus or in the side chain or chains, or be divided between them. They yield acid salts and normal salts, and similarly two series of esters, amides, &c.


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