A Theoretical And Practical Treatise On the Manufacture of Sulphuric Acid ... 1

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A Theoretical And Practical Treatise On the Manufacture of Sulphuric Acid ... 1
Georg Lunge
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The theory propounded by myself, and the very similar one of Sorel, both of which will be found in Chapter IX., equally demand that, other conditions being e(|ual, the vitriol-forming reaction is promoted by a larger amount of water, up to the limit where an excess of water would produce other, injurious, reactions.
Another point to be considered is this, that it is practically im- possible to prevent the loss of some nitre, dissolved in the chamber- acid as nitroso-sulphuric acid, but that the
... tendency of the chamber-acid to retain nitre in this form rapidly increases with its strength. Theory would therefore demand keeping the acid weaker in order to lose less nitre. Whether this is so or not in practice could only be proved by bringing together a great many reliable data, the difficulty of doing which has been pomted out before. It is a/ac/ that sometimes " pale '^ chambers are the conse- quence of giving too little steam, that is, keeping the acid too con- centrated, and that this evil can be remedied by turning on full steam for a short time, when the chamber will become red again.

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