A Treatise On the Theory of Solution Including the Phenomena of Electrolysis

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Fig. 49.
1 Trans. Roy. Soc. Canada, 1882, 21.
2 B. A. Report, 1886, p. 328.
3 Phil. Trans. A, cxciv. 330 (1900).
202 SOLUTION AND ELECTROLYSIS [CH. IX The form of vessel chosen to contain the electrolyte depends on the order of resistance to be measured. For dilute solutions the shapes of figures 48 and 49 will be found convenient, while for more concentrated solutions, those indicated in figures 50 and 51 are suitable.
Fig. 50.
Fig. 51.
The absolute resistances of certain solutions have been d
...e- termined by Kohlrausch by comparison with mercury, and by using one of these solutions in any cell, the constant of that cell can be found once for all. From the observed resistance of any given solution in the cell, the resistance of a centimetre cube, or the specific resistance, can then be calculated. The reciprocal of this, or the conductivity, is a more generally useful constant ; it is conveniently expressed in terms of a unit equal to the reciprocal of an ohm. This unit is sometimes written as a " mho, " a name it is not intended to use in this book.

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