Ammonia And the Nitrides With Special Reference to Their Synthesis
Ammonia And the Nitrides With Special Reference to Their Synthesis
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On allowing the mixture to stand for several days a black explosive powder having the com- position Au 3 N. NH 3 is formed, and on boiling the suspension of this body in water for a quarter of an hour the substance loses ammonia and passes into the free nitride. * By a similar reaction between auroauric oxide and ammonia Raschig obtained a nitride corresponding to Au 3 N 3, according to the equation : 3AuO + 2NH 3 = Au s N 3 + 3H 2 O.
Nitrides of the Alkaline Earths (Ca%N The alkaline earth-met...als, calcium, barium and strontium, all combine readily with nitrogen when heated in the gas, forming nitrides of the general formula M 3 N 2 . Maquennet obtained these bodies by heating an amalgam of the metal in question in an atmosphere of nitrogen. The amalgam was raised slowly to dull redness, the mercury being driven off during this process. The temperature was then increased for a short time to bright redness and the nitride allowed to cool in the gas. The preparation should be carried out in an iron or nickel boat, since platinum is attacked (cf.
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To quickly assess the difficulty of the text, read a short excerpt:
On allowing the mixture to stand for several days a black explosive powder having the com- position Au 3 N. NH 3 is formed, and on boiling the suspension of this body in water for a quarter of an hour the substance loses ammonia and passes into the free nitride. * By a similar reaction between auroauric oxide and ammonia Raschig obtained a nitride corresponding to Au 3 N 3, according to the equation : 3AuO + 2NH 3 = Au s N 3 + 3H 2 O.
Nitrides of the Alkaline Earths (Ca%N The alkaline earth-met...als, calcium, barium and strontium, all combine readily with nitrogen when heated in the gas, forming nitrides of the general formula M 3 N 2 . Maquennet obtained these bodies by heating an amalgam of the metal in question in an atmosphere of nitrogen. The amalgam was raised slowly to dull redness, the mercury being driven off during this process. The temperature was then increased for a short time to bright redness and the nitride allowed to cool in the gas. The preparation should be carried out in an iron or nickel boat, since platinum is attacked (cf.
What to read after Ammonia And the Nitrides With Special Reference to Their Synthesis?
You can find similar books in the "Read Also" column, or choose other free books by Edward B Edward Bradford Maxted to read onlineMoreLess
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