An Experimental Study of the Physical Chemistry of Anaesthesia in ...

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An Experimental Study of the Physical Chemistry of Anaesthesia in ...
Benjamin Moore
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There will be a imall difference in the pressure of water vapour on the two sides, due to there being a stronger solution on the chloroform side, but this is in all cases too minute compared to the pressure of the chloroform vapour to make ■ny appreciable error.
2. Slight differences in dissolved gases gave a disturbance with very dilute chloroform solutions, and this was later obviated by pumping the gases off (vide infra).
Digitized by Google 172 THOMPSON YATES AND JOHNSTON LABORATORIES REPOR
...T 2. Before taking a reading, there must be certainty that each fluid is in equilibrium with its vapour space. This is shown by absence of variation when the apparatus is left at rest.
For rapid and accurate working the mechanical stirring by means of the studs and magnet is indispensable, for even after the lapse of an hour when at rest the solution has not completely discharged its proper amount of chloroform into the vapour space.
When once the control, containing, of course, no chloroform, has been thoroughly stirred it remains constant, and need not be changed at the end of each determination, but can be used throughout an entire experiment.


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