An Introduction to Chemical Crystallography

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Similarly, the monoclinic form of carbon tetrabromide becomes transformed at 46-9 into a cubic modification, with considerable increase of volume (Steinmetz) ; and various polymorphous chloroplatinates behave similarly, according to the investigations of Ries.
The number of polymorphous substances which become transformed at higher temperatures into a cubic (singly refracting) modification is strikingly large ; but, as the above examples show, this may be accompanied by either an in- crease or
...a decrease of volume. The former case is the com- moner, evidently because the majority of substances follow the rule that the form corresponding to the higher tempera- ture possesses the lower density. On the other hand there also exist, in both classes of substances, cases where the POLYMORPHISM 33 modification corresponding to the lower temperature crystal- lises in the cubic system.
As in the matter of symmetry, so also in the matter of . The crystallographic dimensions, is it found that the relations between the different modifications of polymorphous sub- stances are very various.


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