An Introduction to the Study of Chemistry

Cover An Introduction to the Study of Chemistry
An Introduction to the Study of Chemistry
Ira Remsen
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"When a cold object, as a piece of porcelain, is brought into the flame of burning arsine, the arsenic is deposited in the form of a dark spot. This fact is taken advantage of for the purpose of testing for arsenic in examining the stomach and other viscera in a case of suspected poisoning. The method is known as Marsh's test, as it was devised by a chemist by the name of Marsh.
EXPERIMENT 123. Into the flame of the burning hydrogen and arsine produced in the last experiment introduce a piece o
...f por- 266 INTRODUCTION TO CHEMISTRY.
celain, as the bottom of a small porcelain dish or a crucible, and notice the appearance of the spots. Heat by means of a Bunsen burner the tube through which the gas is passing, which should be of hard glass. Just in front of the heated place a thin layer of metallic arsenic, commonly called a mirror of arsenic, will be deposited. This deposit is due to the direct decomposition of the arsine into arsenic and hydrogen by heat. [Compare ammonia, phosphine, and arsine with reference to their stability.


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