An Introductory Course of Quantitative Chemical Analysis, With Explanatory Notes And Stoichiometrical Problems

Cover An Introductory Course of Quantitative Chemical Analysis, With Explanatory Notes And Stoichiometrical Problems
An Introductory Course of Quantitative Chemical Analysis, With Explanatory Notes And Stoichiometrical Problems
Talbot, Henry Paul, 1864-1927
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From the volume of solution required to react with the bleaching powder, calculate the percentage of chlorine in the latter, assuming the titration reaction to be that be- tween chlorine and arsenious acid. Note that one twenti- eth of the total weight of bleaching powder enters into the reaction.
Notes. — I. Bleaching powder may be regarded as con- taining both calcium chloride and hypochlorite. Its effi- ciency, when treated with acids, depends upon the quantity of the latter constituent, sin
...ce the hydrochlorous acid yields as bleaching agents both oxygen and chlorine. It is cus- tomary, however, to express the value of the bleaching agent in terms of available chlorine, as though only that were a factor in its efficiency. The chlorine present as chloride is of course, not available for bleaching purposes, 2. Bleaching powder readily loses chlorine on exposure to the air, as a result of the absorption of carbon dioxide.
The sample must be carefully protected, but even then it is rarely possible to obtain closely agreeing results from sepa- rate samples.


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