Analytical Chemistry

Cover Analytical Chemistry
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Blarez, Chem. News, 91, 39; also Woodman and Talbot, J. Am.
Chem. Soc, 27, p. 1437.
HYDROFLUORIC ACID. 399 ble in acetic acid. On account of its slimy consistency, the precipi- tated calcium fluoride is extremely hard to filter; but by precipi- tating it in the presence of calcium carbonate a mixture is obtained which can be readily filtered. After igniting and treating with acetic acid, the precipitate is changed to soluble calcium acetate and insoluble calcium fluoride; it is now much denser
...and can be filtered readily.
7. Ferric Chloride produces in concentrated solutions of alkali fluorides a white, crystalHne precipitate corresponding to the gen- eral formula [FeFgJXg. These salts, which are analogous to cryo- Ute, [AlFJNa3, are difficultly soluble in water, and their saturated, aqueous solutions do not give the iron reaction upon the addition of potassium sulphocyanate, except after the addition of acid. These complex fluorides also are incompletely decomposed by ammonia, basic fluorides being formed.


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