Applied Colloid Chemistry,;

Cover Applied Colloid Chemistry,;
Applied Colloid Chemistry,;
Wilder D Wilder Dwight Bancroft
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19, 360 (1915).
* Drude's Ann., 9, 434 (1902).
' Harkins states that von Lebch's experiments with dilute caustic soda solution are inaccurate.
• Zeit. phys. Chem., 86, 645 (1914).
Digitized by VjOOQIC 128 APPLIED COLLOID CHEMISTRY picric acid, salicylic acid, and mercurous sulphate are adsorbed from aqueous solution by mercury, the surface tension of the mercury being lowered as a result of the adsorption. In all four cases the amoimts adsorbed varied with the concentration approximately accord
...ing to a formula of the type foimd to hold for adsorption from solution by a solid.
The adsoiption of hydroxyl means practically a concentrating of alkaU at the surface of the benzene and consequently a closely adhering film of water. This accoimts for Wilson's observation that the drops of chloroform were readily wetted by an alkaline solution. The presence of the surface film of caustic soda solu- tion also accounts for the decreased mobility observed by Wilson.
Digitized by VjOOQIC CHAPTER IV SURFACE TENSION— BROWNIAN MOVEMENTS Adsokption and Surface Tension When a substance dissolves in a liquid, the surface tension between the liquid and the vapor changes, increasing in some cases and decreasing in others.


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