Are Electrolytes Completely Ionized At Infinite Dilution
Are Electrolytes Completely Ionized At Infinite Dilution
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KC1 sat. KC1 Hx Hx H 2 (1 atmos. ) Pt. 0. 5266 zero r zero e <-* ^ It can be seen that since we know only the observed value of the system and the value of the pole potential of the calomel cell, 1 we can not arrive at a value of the pole potential of the hydrogen electrode "e, " until we know the value of the contact potential "r. " As a matter of direct experimentation it is not possible to determine "r" but from the indirect experimentation of Fales and Vosburgh ~ it would seem that the value of the contact potential between saturated potassium chloride and 1 M. Hydrochloric acid and between saturated potassium chloride and 0. 1 M. Hydrochloric acid is zero 3 ; and inferen- tially by a similar process of reasoning it likewise would seem that the contact potential between saturated potassium chloride and hydrochloric acid solutions of less concentration than 0. 1 M. Would be zero. If for 1 The pole potential of the sat. KC1 calomel electrode at 25 is equal to 0. 5266 volt on the basis that the value of the normal calomel cell Hg HgCl 1 M.
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You can find similar books in the "Read Also" column, or choose other free books by Harold Eugene Robertson to read online
To quickly assess the difficulty of the text, read a short excerpt:
KC1 sat. KC1 Hx Hx H 2 (1 atmos. ) Pt. 0. 5266 zero r zero e <-* ^ It can be seen that since we know only the observed value of the system and the value of the pole potential of the calomel cell, 1 we can not arrive at a value of the pole potential of the hydrogen electrode "e, " until we know the value of the contact potential "r. " As a matter of direct experimentation it is not possible to determine "r" but from the indirect experimentation of Fales and Vosburgh ~ it would seem that the value of the contact potential between saturated potassium chloride and 1 M. Hydrochloric acid and between saturated potassium chloride and 0. 1 M. Hydrochloric acid is zero 3 ; and inferen- tially by a similar process of reasoning it likewise would seem that the contact potential between saturated potassium chloride and hydrochloric acid solutions of less concentration than 0. 1 M. Would be zero. If for 1 The pole potential of the sat. KC1 calomel electrode at 25 is equal to 0. 5266 volt on the basis that the value of the normal calomel cell Hg HgCl 1 M.
What to read after Are Electrolytes Completely Ionized At Infinite Dilution?
You can find similar books in the "Read Also" column, or choose other free books by Harold Eugene Robertson to read online
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