Atomic Form With Special Reference to the Configuration of the Carbon Atom

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In the formula COOH I HO C-H I H C H I COOH if it be allowed to rotate the molecule in the plane of the paper, and also around its longer axis, no effective variation can be made. If however only one change of position is allowed, viz. , a rotation in the plane of the paper, two different formulae can be designed, viz. : COOH COOH I I HO-C-H H-C-OH I I H C H H C H I I COOH COOH 84 ATOMIC FORM This leaves us without any further rearrangement possible for Crassulaic Malic Acid and even these form...ulae are based upon the assumption of a difference in form between the back and front of the molecule, which is consistent with the view that the carbons have a definite geometric form, but which would not be appropriate, if the carbon is represented by a sphere with equal attractions in four different directions in the plane of the paper in which case, rotation around the longer axis would be possible. To meet this difficulty the following formulae have been designed : I. II. III. COOH COOH COOH I I I HO-C-H HO-C-H HO-C-H I I HOOC C H H C COOH H C H I I I H H COOH Formulae I.

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Atomic Form With Special Reference to the Configuration of the Carbon Atom
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