Biochemical Research 1912 13

Cover Biochemical Research 1912 13
Biochemical Research 1912 13
University of Chicago Biochemical Laboratory
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525 size in liquid and vapor, or do not in other ways gain energy. 1 I believe the internal latent heat of vaporization consists of at least three parts, not two as is often stated, these three parts are : (i) the heat consumed in expanding against external pressure, or E; (2), the heat consumed in overcoming molec- ular cohesion, or A; (3), heat consumed in increasing internal molecular potential energy by expanding the molecule, or increasing its energy of rotation, or I. This last factor is ...often overlooked. If L is the total latent heat of vaporiza- tion the expression should be : L E I == A. And if mole- cules attract inversely as the square of the distance we should have (I, E I)/(V^ VDJ - /.
There are two principal reasons why it cannot be assumed that all the internal latent heat of vaporization goes to in- creasing the potential energy by separating the molecules against the force of their molecular cohesions. The first of these reasons is that the value "b, " of van der Waals' equa- tion, has to be taken larger in the vapor than in the liquid for some distance below the critical point.


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