Chemistry for Students

Cover Chemistry for Students
Chemistry for Students
Alexander W Alexander William Williamson
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Cupric Nitrate (Cu (N O 3 ) 2 ). This salt is formed by dissolving metallic copper in nitric acid. It is very soluble and crystallizes, sometimes with three molecules of water, sometimes with six molecules. It cannot be dried without decomposition. 216 CUPRIC SULPHA TE. 172 There are two chlorides of copper a white cuprous chlo- ride (Cu 2 Cl 2 ), which dissolves in hydrochloric acid, and a cupric chloride, which crystallizes from water in needle- shaped crystals of the composition CuCl 2 (H 2
...O) 2 .
With iodine copper forms only one compound, viz. The cuprous iodide Cu 2 ! 2 ; and when cupric sulphate is mixed with potassic iodide this salt is precipitated, while iodine is liberated at the same time 2 Cu S O 4 + 4 K I = Cu 2 ! 2 + I 2 + 2 K 2 S O 4 .
Cupric sulphide is easily and completely thrown down as a black precipitate by the action of sulphuretted hydrogen on an acid solution of a salt of copper. There is also a cuprous sulphide Cu 2 S, which is formed during the pro- cess of smelting.


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