Chemistry of the Carbon Compounds: Or, Organic Chemistry

Cover Chemistry of the Carbon Compounds: Or, Organic Chemistry
Chemistry of the Carbon Compounds: Or, Organic Chemistry
Victor Von Richter
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Its derivatives, containing alkyl or phenyl groups attached to the N>atom, are similarly produced by the action of primary amines upon acetophenone-acetoacetic ester (p. 546).
(I, 4).Diphenylpyrrol-j3^arboxylic Acid, C4H(CjH5),(NH).COjH, from acetophenone-benzoyl acetic ester and ammonia (p. 495), melts at 261° {Berichte, ai. 3060).
KETONIC ACIDS.
a-PyrroylCarbozylic Acid,C4H,(NH).C0.C0,H, Pyrryl GLyoxylic Acid, is produced by the oxidation of a-pyrryl methyl ketone (p. 544) with alkaline po- t
...assium permanganate {Berichte, 17, 2949). It crystallizes from water in yellow needles, melting with decomposition at 74-76^. They become anhydrous when placed over sulphuric acid. The anhydrous acid, from benzene, consists of yellow needles, decomposing about 1 14^ Ferric chloride imparts an intense red color to the aqueous solution. When fused with caustic potash, it becomes a-pyrrol-car- boxylic acid {Berichte^ 19, 1957).
Pyrryl-mcthyl-ketone Carboxylic Acid, C4H,(NH)^^^-^», Accto- pyrrol carboxylic acid.


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