College Physics

Cover College Physics
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Owing to the film of hydrogen which is collected upon the mercury surface, the counter E. M. F. of polarization is almost equal to the direct E.M. F. of the cell, and the current is reduced almost to zero. The cell is polarized. By dropping into the cell a piece of mercuric chloride as large as the head of a pin, the cell is instantly restored to action.
The mercuric chloride reacts upon the free hydrogen, form- ing hydrochloric acid (HCl) and free mercury. This disposes of the polarizing film
...of hydrogen, and the signals are given clearly so long as the mercuric chloride lasts. Any substance which unites chemically with the hydrogen film upon the posi- tive plate, and thus reduces polarization, is termed a depolarizer.
In the construction of cells, care must be taken either to have S29 330 COLLEGE PHYSICS a,B+ Fig. 149.
no polarization or to supply the cell with a depolarizer. In the following paragraphs only such cells have been described as are found in common use.
290. The Daniell Cell.


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