Copper Refining

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It takes three tanks in cascade to bring the copper and arsenic down to 0. 1 per cent or less. The first tank will operate at about 85 per cent current efficiency and produce cathodes, which may with reasonable safety be included in the fine copper output ; the second will run at perhaps 50 per cent efficiency and the cathodes reserved for casting copper or anode changes; the last tank runs at a very low copper efficiency and produces a sludge consisting of about half copper and half metallic a...rsenic. Much of the latter can be eliminated from this by roasting and sublimation, if desired. Such insoluble anode tanks evolve arseniuretted hydrogen, which is very poisonous, and they should therefore be located out of doors.
This method is limited by the permissible amount of impoverishment of the electrolyte in copper; if carried to extremes it is evident that the whole copper content of the electrolyte would be withdrawn, the acid being corre- spondingly increased. On the other hand, when nickel is practically absent from the anodes and the copper withdrawals necessary to hold down the arsenic do not exceed the normal growth of copper in the electrolyte, it is a satisfactory solution of the purification problem.


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