Detection And Determination of Small Quantities of Ethyl And Methyl Alcohol And

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, 1901, 34: 3354.
J. Amer. Chem. Soc. , 1898, 20: 293 Loc. Cit.
DETECTION AND DETERMINATION OF ALCOHOLS, ETC. 3 distilling it, using an ordinary distilling flask, from 94 to 100 per cent of the total alcohol could be easily concentrated in a relatively small volume of distillate, as is shown from the following experiments selected from a number made to test this point : Experiment 1. To 500 cc of water containing 1 gram of absolute alcohol (0. 2 per cent by weight) there were added 200 grams of
... calcium chlorid and this solution was distilled from a 1 liter distilling flask, 150 cc of distillate being collected. To this distillate there were added 50 grams of calcium chlorid and a 50 cc solution was distilled from it. This distillate gave at 17. 5 C. , with the Zeiss immersion refracto- meter, a reading of 18. 2, equivalent to 2 per cent of alcohol, a 100 per cent recovery.
Experiment 2. Five hundred cubic centimeters of 0. 19 per cent alcohol were treated as in experiment 1, save that of the first distillate but 100 cc were collected.


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