Differential Capacity of Stainless Steel in Potassium Chloride Solutions During Potentiostatic And Galvanostatic Polarization
Differential Capacity of Stainless Steel in Potassium Chloride Solutions During Potentiostatic And Galvanostatic Polarization
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In our eReader you can find the full English version of the book. Read Differential Capacity of Stainless Steel in Potassium Chloride Solutions During Potentiostatic And Galvanostatic Polarization Online - link to read the book on full screen. Our eReader also allows you to upload and read Pdf, Txt, ePub and fb2 books. In the Mini eReder on the page below you can quickly view all pages of the book - Read Book Differential Capacity of Stainless Steel in Potassium Chloride Solutions During Potentiostatic And Galvanostatic Polarization
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As the potential is shifted positive past the reversible potential, oxidation of the absorbed hydrogen atoms from the metal will occur, causing an increase in the capacity value measured. The accumulation of the resulting hydronium ion at the interface will cause a decrease in pH and a produce a positive shift in the reversible potential of the reaction. If the interfacial pH becomes low enough, hydrogen evolution will again become energetically feasible. The interfacial pH necessary to allow h...ydronium ion reduction in the potential range of the cathodic loop (-0.30 to 0.0 V) is calculated from equation 7 as 0.91 to - 4-. 10. If it is assumed that all of the hydrogen produced at -0.700 V ( ,^.2.4 coul) is absorbed by the stainless steel and then emitted into an approximately .
100 A double layer, an interfacial pH of -4.1 is calculated.
Since only a fraction of the hydrogen produced is expected to be absorbed, this is obviously an approximation.
With the present data it is not possible to make the distinction between one broad capacity peak or two separate, narrower peaks in the active-passive transition region.
What to read after Differential Capacity of Stainless Steel in Potassium Chloride Solutions During Potentiostatic And Galvanostatic Polarization?
You can find similar books in the "Read Also" column, or choose other free books by Fiorino, M. Elaine Curley to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
As the potential is shifted positive past the reversible potential, oxidation of the absorbed hydrogen atoms from the metal will occur, causing an increase in the capacity value measured. The accumulation of the resulting hydronium ion at the interface will cause a decrease in pH and a produce a positive shift in the reversible potential of the reaction. If the interfacial pH becomes low enough, hydrogen evolution will again become energetically feasible. The interfacial pH necessary to allow h...ydronium ion reduction in the potential range of the cathodic loop (-0.30 to 0.0 V) is calculated from equation 7 as 0.91 to - 4-. 10. If it is assumed that all of the hydrogen produced at -0.700 V ( ,^.2.4 coul) is absorbed by the stainless steel and then emitted into an approximately .
100 A double layer, an interfacial pH of -4.1 is calculated.
Since only a fraction of the hydrogen produced is expected to be absorbed, this is obviously an approximation.
With the present data it is not possible to make the distinction between one broad capacity peak or two separate, narrower peaks in the active-passive transition region.
What to read after Differential Capacity of Stainless Steel in Potassium Chloride Solutions During Potentiostatic And Galvanostatic Polarization?
You can find similar books in the "Read Also" column, or choose other free books by Fiorino, M. Elaine Curley to read onlineMoreLess
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