Electro Chemical Analysis

Cover Electro Chemical Analysis
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Ch. , 18, 523; Luckow, Z. F. A. Ch. , 19, 16; Bergmann and Fresenius, Z. F. A. Ch. , 19, 314; Riche, Z. F. A. Ch. , 21, 116, 119; Classen and v. Reis, Ber. , 14, 1622, 2771; Schucht, Z. F. A. Ch. , 21, 493; Kohn and Wood- gate, Jour. Soc. Chem. Industry, 8, 256. These metals are precipitated from solutions of their double cyanides, double oxalates, and sulphates mixed with alkaline acetates, tartrates and citrates, or from ammoniacal solutions. The latter seem best adapted for nickel deposition...s, the presence of ammonium sulphate or sodium phosphate being favorable to the precipitation. DETERMINATION OF METALS NICKEL, COBALT. 73 Fresenius and Bergmann, who have carried out a series of experiments with nickel and cobalt, give the following as satisfactory conditions : 50 c. C. Nickel solution (=0. 1233 gram nickel), 100 c. C. Ammonia (sp. Gr. 0. 96), io c. C. Ammonium sulphate (305 grams of the salt in I litre of water), 100 c. C. Of water; sepa- FIG. 23. Ration of the electrodes j~~X cm.

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