Experimental And Theoretical Applications of Thermodynamics to Chemistry
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85 SO.
3. 42 3. 0 Water 3. 6 3. 3 CS 9 .
3. 26 2. 75 Alcohol 4. 48 3. 7 "^2 ' For substances for which it has apparently been possible to determine C with some degree of accuracy (the most uncertain are evidently oxygen and nitrogen), we find approximately (39) C=l. La.
Table X contains the values of C calculated ac- cording to equation (39) for a considerable num- ber of substances. These are the values which we shall use hereafter in the calculation of chemical equilibria.
TABLE X H 2 2. 2 N ...Z 0....
3, 3 CH A 2. 5 jv H 9 S..
30 N* .... 2. 6 2^ * SO* ....
3, 3 Oo 2. 8 CO* ....
3fl CO.
3. 6 v^g C8 9 31 CL 3. 0 NH S 3, 3 / g 4. 0 H0..
37 HCl..
. 3. 0 gw COL 3. 1 Benzol 3. 1 Alcohol 4. 1 Ether 3. 3 Acetone 3. 7 Propyl acetate . . 3. 8 NO. . . (about) 3. 7 CHC1 3 .. 3. 2 76 THERMODYNAMICS AND CHEMISTRY From these figures we may conclude that for substances which do not associate, C increases quite regularly with the boiling point, so that we can interpolate with a fair degree of certainty the values of O for other substances which are not associated ; whereas associated substances (water, alcohol, acetone, probably NO, perhaps also CO) have distinctly higher values than would corre- spond to their boiling points.
What to read after Experimental And Theoretical Applications of Thermodynamics to Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Nernst, Walther, 1864-1941 to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
85 SO.
3. 42 3. 0 Water 3. 6 3. 3 CS 9 .
3. 26 2. 75 Alcohol 4. 48 3. 7 "^2 ' For substances for which it has apparently been possible to determine C with some degree of accuracy (the most uncertain are evidently oxygen and nitrogen), we find approximately (39) C=l. La.
Table X contains the values of C calculated ac- cording to equation (39) for a considerable num- ber of substances. These are the values which we shall use hereafter in the calculation of chemical equilibria.
TABLE X H 2 2. 2 N ...Z 0....
3, 3 CH A 2. 5 jv H 9 S..
30 N* .... 2. 6 2^ * SO* ....
3, 3 Oo 2. 8 CO* ....
3fl CO.
3. 6 v^g C8 9 31 CL 3. 0 NH S 3, 3 / g 4. 0 H0..
37 HCl..
. 3. 0 gw COL 3. 1 Benzol 3. 1 Alcohol 4. 1 Ether 3. 3 Acetone 3. 7 Propyl acetate . . 3. 8 NO. . . (about) 3. 7 CHC1 3 .. 3. 2 76 THERMODYNAMICS AND CHEMISTRY From these figures we may conclude that for substances which do not associate, C increases quite regularly with the boiling point, so that we can interpolate with a fair degree of certainty the values of O for other substances which are not associated ; whereas associated substances (water, alcohol, acetone, probably NO, perhaps also CO) have distinctly higher values than would corre- spond to their boiling points.
What to read after Experimental And Theoretical Applications of Thermodynamics to Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by Nernst, Walther, 1864-1941 to read onlineMoreLess
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