Fluidity And Plasticity

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Fluidity And Plasticity
Eugene Cook Bingham
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The experiments of Stables and Wilson need confirmation and 254 SUPERFICIAL FLUIDITY 255 extension with our more recent knowledge of the nature of flow in mind, but whatever the surface of a given saponin solution may be, we may profitably distinguish three typical cases: (A) where the superficial layer is a true solution but of different concen- tration from the interior and is in contact with it own vapor or some gas; (B) where the surface is made up of a layer of immisci- ble liquid, which m
...ay be so thin as to be imperceptible by ordi- nary means; (C) where the surface is formed either by a continuous solid or by solid particles in more or less intimate contact with each other. It is evident that in the last two cases we are dealing not with the superficial fluidity of the liquid but of a heterogene- ous mixture of liquid-liquid or solid-liquid respectively.
Soap solutions perhaps afford the best examples of the first case and if such solutions have extraordinarily high superficial viscosity, it serves to explain the stability of the soap bubble.


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