Further Studies On Phenolic Hexamethylenetetramine Compounds

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88 To represent the above results we can write the equation (CH 2 ) C N 4 + 18. 55(0) = 6C0 2 = 5. 89H 2 O + 1. 89N 2 + 0. 22 HNO 3 + 1036. 9 Cal.
We know that 6(C) + 12(0) = 6C0 2 + 6 X 96. 98 Cal. (1) (Land, and Born. , 4th Ed. , p. 855) 11. 78(H) + 5. 89(0) = 5. 89H 2 O + 68. 357 X 5. 89 Cal. (2) (Land, and Born. , 4th Ed. , p. 850) 0. 22(H) -f- 0. 22(N) -f 0. 66(O) = 0. 22HNO 3 + 41. 60 Cal. (3) (Land, and Born. , 4th Ed. , p. 854) Substituting these three equations in the found equa- tion
...above, we have: 6(C) + 12(H) +4(N) = (CH 2 )eN 4 43. 18 Cal. Therefore the heat of formation of hexamethylene- tetramine = 43. 18 Cal.
(e) Heat of formation of phenol Berthelot 1 gives the heat of combustion of phenol at constant pressure and 18 C. As 736. 00 Cal. Per mole.
Required: 6(C) + 6(H) + (O) = C 6 H 6 O + x Cal. Found: C 6 H 6 O + 14(O) = 60 O 2 + 3H 2 O + 736. 00 Cal. We know that: 6(C) + 12(0) = 60 2 + 96. 98 Cal. * (1) 3H 2 + 30 = 3H 2 O + 68. 36 X 3 Cal. (2) Substituting Equations 1 and 2 in the found equa- tion we obtain 6(C) + 6(H) + O = C 6 H 6 O + 50.


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