General Chemistry for Colleges

Cover General Chemistry for Colleges
General Chemistry for Colleges
Smith Alexander
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It appears, therefore, that iodine has more affinity for oxygen than has bromine.
The Oxide and Oxygen Adds of Iodine. — The f oDowing are the familiar acids and their corresponding salts: HIOs Iodic acid, EIO, Potassium iodate, [HIO4 Periodic acid], NalOi Sodium periodate, HJOe Periodic acid, NasHsIO, Disodium periodate.
There is one oxide, iodic anhydride 1,06.
Sodium Iodate NalOs is found in Chile saltpeter. It may be made, in much the same fashion as are the chlorates and bromates (pp. 313,
... 318), by adding powdered iodine to a hot solu- tion of potassium or sodium hydroxide. It is disodium periodate NatHsIOe, however, which, being least soluble, crystallizes out.
Iodic Add HIOs is formed by passing chlorine through iodine suspended in water. The action is parallel to that of chlorine on bromine-water: 5HaO + HtO + I,-*2HI0i + SHQ.
A still better way is to boil iodine with aqueous nitric add (9.V.).
The latter gives up oxygen readily, and is here used solely on tUs Digitized by Google OXIDEB AND OXYGEN ACIDS, THE HAIiOOENS 319 account.


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