Hand book of Chemistry volume 11

Cover Hand book of Chemistry volume 11
Hand book of Chemistry volume 11
Leopold Gmelin
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.. .. .. .. . 48 . .. .. .. . 19-90 . .. .. .. . 17-54 . .. . 284 . .. .. .. . 100-00 . .. .. .. . 100-00 GUAIACONIC ACID. 155 Primary Nucleus C 38 !! 24 ; Oxygen-nucleus Guaiaconic Acid. C 38 H 20 10 = C^H^OSO 6 . HADEHCH. Dissertation uber Bestandth. Des Guajakharzes. Gottingen, 1862 ; J. Pr. Chem. 87, 321 ; Kopp's Jahresber. 1862, 466. Occurs in guaiac-resin to the amount of about 70 per cent. The alcoholic mother-liquor from which the guaiacic acid has been precipitated by alcoholic potash,... in the preparation of guaiacic acid, is evaporated, at 30, to a thick syrup, and mixed with absolute alcohol, whereby a little of the potash-salt of guaiacic acid is thrown down. This last body is removed ; carbonic acid is passed into the filtrate ; the liquid, separated from carbonate of potash and mixed with water and a little hydrochloric acid, is heated to drive off the alcohol ; and the resin thereby separated is washed with warm water. On cooling, the resin forms a brittle, brown mass, which is resolved, by treatment with ether, into guaiaconic acid soluble in ether, and guaiac beta- resin insoluble in that menstruum.

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