Heavy Metal Complexation With Naturally Occurring Organic Ligands in Wetland Ecosystems

Cover Heavy Metal Complexation With Naturally Occurring Organic Ligands in Wetland Ecosystems
Heavy Metal Complexation With Naturally Occurring Organic Ligands in Wetland Ecosystems
Tuschall, John Richard
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The lack of an observed correlation of manganese with F^S or DOC was expected since, according to equilibrium calculations (MINEQL), Mn + 2 was the predominant form of manganese under all experimental conditions; thus precipitation as MnS or complexation with DOC should not have occurred.
4. Zinc Zinc was added to the microcosms to an initial level of approxi- mately 100 yg/L, and after 120 h the aqueous concentrations of zinc ranged from 20 to 86 yg/L, corresponding to reductions of 18-84% (Ta
...ble VI-6). The experimental F statistics (Table VI-7) indicate that pH and FUS were correlated with rates of zinc losses and that pH-HoS interaction was significant. These results are similar to those obtained for cadmium, which is not surprising since the two metals are similar chemically (Cotton and Wilkinson 1966). For exam- ple, both cadmium and zinc are associated with naturally occurring organic matter at approximately equal strength that typically is inter- mediate between the strong copper-organic complexes and the weaker 192 manganese-organic complexes (Irving and Williams 1948; Mantoura et al.

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