Industrial Gases

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) for the original water gas.
About 450 ft. 3 /hr. Of the 16 % carbon monoxide gas was passed through the catalytic chambers, which had a volume of about i "8 ft. 3, corresponding to a " space velocity " of 250 ft. 3 /ft. 3 catalyst space/hour, referred to the 16 % carbon monoxide gas, or of 128 referred to the final gas. The cost of conversion of the water gas into the final product is given as 176^71000 ft. 3 of the latter ; this figure would appear to be low and in any case does not include
...any overhead charges.
The Manufacture of Phosgene Carbonyl chloride, or phosgene, is an industrial gas which may be conveniently described at this point on account of its manufacture from carbon monoxide. By passing a mixture of carbon monoxide and chlorine over platinum sponge at 400 C. , combination takes place yielding phosgene, according to the following reversible reaction : CO + C1 2 ^COC1 2 +22, 950 calories.
The equilibrium is given below for a pressure of one atmosphere, the values being calculated according to the CARBON MONOXIDE 253 Nernst Heat Theorem (cf.


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