Introduction to General Inorganic Chemistry

Cover Introduction to General Inorganic Chemistry
Introduction to General Inorganic Chemistry
Smith Alexander
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These equilibria are all of precisely the same nature as that of phosphorus pentachloride vapor (p. 255), and the discussion of the latter should be reexamined and applied by the reader. The sole difference is that here change in volume is effected, not by compression or by release of pressure, but by removing or adding water. The adjustment to a condition of equilibrium, however, seems to be instan- taneous where ions are concerned, while in other chemical actions it always takes a perceptible
..., and often a considerable interval of time.
Using Cj, Cj, and Cg for the molecular concentrations (numbers of moles per liter) of the molecules, and the two ions, respectively, we have an equilibrium constant (of. p. 254), in this case called the ionization constant : „ „ O3 X Oj K=—^^ When we dissolve a single substance which gives only two ions, the molecular concentrations of the ions are necessarily equal. Hence, C ^ in such a case, -^ = K. When some other ionogen with a common ion is present, however, the values of C^ and Cj will be different.


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