Lubrication And Lubricants : a Treatise On the Theory And Practice of Lubrication, And On the Nature, Properties, And Testing of Lubricants

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Lubrication And Lubricants : a Treatise On the Theory And Practice of Lubrication, And On the Nature, Properties, And Testing of Lubricants
Archbutt, Leonard
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in weight.
Table LXIV. (p. 234) contains the results obtained by treating in this way the unsaponinable matter (mixed alcohols) from sperm oil, wool fat, beeswax, and carnauba wax; also the results theoretically yielded by some alcohols known to occur in fats and waxes.
The alcohols of sperm oil are unknown ; according to Lewkowitsch they belong for the most part, if not wholly, to the ethylene series. ' The alcohols of wool fat are also partly unknown, but cholesterol and isocholesterol occur
...in them to a large extent, and ceryl alcohol also is present. Myricyl alcohol is the chief part of the unsaponinable matter from carnauba wax and beeswax ; in the latter hydrocarbons occur to the extent of 15-17 per cent., which accounts for the low saponification value of the acetylated product. Cetyl palmitate is the chief constituent of spermaceti, in which octadecyl alcohol also occurs.
Analysis of Mixtures containing Sperm Oil or Wool Fat and Mineral Oil, — (a) When a mixture containing sperm oil or wool fat and mineral oil is saponified, the unsaponinable matter extracted from the soap solution by ether contains the whole of the mineral oil together with the mixed alcohols of the wax, and in order to determine the percentage of mineral oil directly the alcohols must be separated.


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